12150-46-8, 1,1-Bis(diphenylphosphino)ferrocene is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
A reaction flask was charged with 1 , l’-bis(diphenylphosphino)ferrocene (1.84 g, 3.32 mmol), bis(l,5-cyclooctadiene)nickel (0.75 g, 2.80 mmol) and oxygen-free toluene (10 mL) under a nitrogen atmosphere in a glovebox. After stirring for 4 h at room temperature, hexanes (40 mL) were added to the reaction mixture. The reaction mixture was allowed to stand overnight, and then the solvents were decanted off and the orange-yellow solid remaining was washed with hexanes. The solid was dried under vacuum to give the title compound as an orange-yellow solid (1.86 g, 78percent yield). 31P NMR (benzene-^): delta 38.4 (s).
12150-46-8, The synthetic route of 12150-46-8 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; E. I. DU PONT DE NEMOURS AND COMPANY; WO2009/61991; (2009); A1;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate