13885-09-1, 2-(Diphenylphosphino)biphenyl is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
A solution of CuI (0.019 g, 0.1 mmol) in CH3CN(5 mL)was added to a stirred solution of 2-PBI (0.020 g, 0.1 mmol)and 2-(Dpp)bp (0.034 g, 0.1 mmol) in CH2Cl2(5 mL). Themixture was stirred for 5 min, with no visible precipitation.After filtration, the filtrate was set aside for evaporation inair. Yellow block crystals of complex 3 were obtained after3 days. Yield: 35.1 mg (48.5percent, based on Cu). Anal. Calc. for3 C36H28N3P1Cu1I1:C, 59.73; H, 3.87; N, 5.81. Found (percent):C, 59.72 H, 3.84; N, 5.78. IR (KBr pellet, cm?1): 3443sh,3077vs, 3054s, 1610w, 1491m, 1443vs, 1326m, 1114w,805m, 746vs, 711vs, 522m.
13885-09-1, The synthetic route of 13885-09-1 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Chen, Di; Chai, Wen-Xiang; Song, Li; Transition Metal Chemistry; vol. 43; 6; (2018); p. 517 – 527;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate