166330-10-5, (Oxybis(2,1-phenylene))bis(diphenylphosphine) is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
General procedure: An oven-dried 10 mL screw-capped vial was charged with [(allyl)PdCl]2 (3.7 mg, 0.010 mmol),1a (0.12 g, 0.20 mmol) and toluene (1 mL) under a gentle stream of nitrogen. The vessel washeated at 140 C for 24 h followed by cooling. An aqueous solution of H2O2 (ca. 30%, a fewdrops) was added, and the mixture was stirred at room temperature for 1 h. The mixture wasfiltered through a short pad of silica gel, and the pad was washed with EtOAc. The filtrate wasevaporated, and the residue was purified by GPC to give 2a (70 mg, 93%) as a yellowish whitesolid., 166330-10-5
As the paragraph descriping shows that 166330-10-5 is playing an increasingly important role.
Reference£º
Article; Baba, Katsuaki; Masuya, Yoshihiro; Chatani, Naoto; Tobisu, Mamoru; Chemistry Letters; vol. 46; 9; (2017); p. 1296 – 1299;,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate