932710-63-9, 4-(Di-tert-butylphosphino)-N,N-dimethylaniline is a chiral-phosphine-ligands compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
To a solution of {Te((2,6-OCH3)2C6H3)}2 (0.053 g, 0.1 mmol) inacetonitrile (5 mL), PdI2 (0.036 g, 0.1 mmol) was added and thesolution was stirred for 2.5 h. In the next step, (4-(N,N-dimethylamino)phenyl)di-tert-butyl phosphine (0.053 g, 0.2 mmol) wasadded and the mixture was stirred for a further 2.5 h. The turbidsolution was filtered through filter paper followed by filtrationthrough Celite. The slow evaporation of solvent afforded air-stabledark red crystals suitable for X-ray analysis. Yield: 0.035 g, 45%based on PdI2. Melting Point: 187-189 C. Analytical data for 2(after drying in vacuum), C52H80I2N4O4P2Pd2Te2 (1608.94 g mol-1):Calcd. C = 38.82%, H = 5.01%, N = 3.48%. Found: C = 40.11%,H = 5.44%, N = 3.52%. FTIR (KBr): 3077 [nus(C-H)Ar.]; 2962[nuas(C-H)Aliph.]; 2891 [nus(C-H)Aliph.]; 1598, 1511, 1464, [nus(C=C)];1245 [nuas(C-O-C)]; 1100 [nus(C-O-C)]; 1017, 945 [deltaip(C=C-H)];812, 764 [deltaop(C=C-H)]; 501 [nu(P-C)].
The synthetic route of 932710-63-9 has been constantly updated, and we look forward to future research findings.
Reference£º
Article; Cechin, Camila N.; Paz, Alisson V.; Piquini, Paulo C.; Bevilacqua, Andressa C.; Pineda, Nahum R.; Fagundes, Natalia V.; Abram, Ulrich; Lang, Ernesto S.; Tirloni, Barbara; Polyhedron; vol. 177; (2020);,
Phosphine ligand
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate