Related Products of 564483-18-7. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 564483-18-7, Name is 2-(Dicyclohexylphosphino)-2′,4′,6′-tri-i-propyl-1,1′-biphenyl. In a document type is Article, introducing its new discovery.
An efficient method for the selective mono-N-arylation of 1-aminoazoles to provide a range of N-aryl-1-aminoazoles in good yields is described. This process based on the use of tris(dibenzylideneacetone) dipalladium associated to Xphos as the catalyst system is general, and allows the coupling to proceed, for the first time, with a variety of cheaper and less reactive aryl chlorides. The sequential combination of selective monoarylation using aryl chlorides and a second N-arylation reaction using (hetero)aryl bromides and iodides proved to be useful for the rapid construction of non-symmetrical N,N’-diaryl-1- aminoindoles in good yields.
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Reference：
Phosphine ligand,
Chiral phosphine ligands in asymmetric synthesis. Molecular structure and absolute configuration of (1,5-cyclooctadiene)-(2S,3S)-2,3-bis(diphenylphosphino)butanerhodium(I) perchlorate tetrahydrofuran solvate